Frame transformation relations for fluxional symmetric rotor dimers.

نویسندگان

  • Horace T Crogman
  • William G Harter
چکیده

The theory of frame transformation relation connecting body oriented angular momentum states and lab weakly coupled momentum states have been extended from rotor-electron to rotor-dimer systems. Coupling schemes are analyzed for weak and strong cases of correlation between lab and two different rotor body frames. It is shown that the frame transformation relation is a purely quantum effect at low angular momentum but an approach to a classical limit for high J. Symmetry analysis of frame transformation is compared to eigensolutions of model coupling Hamiltonian.

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عنوان ژورنال:
  • The Journal of chemical physics

دوره 121 19  شماره 

صفحات  -

تاریخ انتشار 2004